OK, not the greatest chart, but this is all time % caught stealing.
Here's the link for a better look if you want:
http://www.baseball-reference.com/lead ... tive.shtml
Rank Player (yrs, age) Caught Stealing % Throws
1. Yadier Molina (13, 33) 43.04 R
2. Rene Rivera (8, 32) 37.26 R
3. Ryan Hanigan (10, 35) 37.22 R
4. Salvador Perez (6, 26) 35.43 R
5. David Ross (15, 39) 35.04 R
6. Gerald Laird (13, 36) 34.85 R
7. Yan Gomes (5, 28) 34.62 R
8. Miguel Olivo (13, 37) 33.77 R
9. A.J. Ellis (9, 35) 33.61 R
10. Wilson Ramos (7, 28) 33.56 R
11. Buster Posey (8, 29) 33.53 R
12. Joe Mauer (13, 33) 33.21 R
13. Drew Butera (7, 32) 33.17 R
14. Humberto Quintero 33.10 R
15. Matt Wieters (8, 30) 32.92 R
16. Russell Martin (11, 33) 32.16 R
17. Geronimo Gil (6, 40) 31.22 R
18. Welington Castillo (7, 29) 30.41 R
19. Alex Avila (8, 29) 29.28 R
20. Chris Stewart (10, 34) 29.21 R
21. Ronny Paulino (8, 35) 29.20 R
22. Mike Zunino (4, 25) 28.43 R
23. Dioner Navarro (13, 32) 28.06 R
24. Miguel Montero (11, 32) 27.89 R
25. Brayan Pena (12, 34) 27.76 R
26. Nick Hundley (9, 32) 27.47 R
27. Jeff Mathis (12, 33) 27.45 R
28. Jonathan Lucroy (7, 30)27.41 R
29. Geovany Soto (12, 33)27.27 R
30. Carlos Ruiz (11, 37) 27.18 R
31. Derek Norris (5, 27) 26.89 R
32. J.P. Arencibia (6, 30) 26.69 R
33. Jason Castro (6, 29) 25.82 R
34. Brian McCann (12, 32) 25.59 R
35. Bobby Wilson (8, 33) 25.49 R
36. Carlos Santana (7, 30) 25.27 R
37. Devin Mesoraco (6, 28) 25.24 R
38. Chris Iannetta (11, 33) 25.11 R
39. Tyler Flowers (8, 30) 24.71 R
40. Kurt Suzuki (10, 32) 24.49 R[/list]